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By Rudi van Eldik

Advances in Inorganic Chemistry offers well timed and informative summaries of the present growth in quite a few topic parts inside of inorganic chemistry starting from bio-inorganic to strong nation reports. Thisacclaimed serial beneficial properties experiences written via specialists within the region and is an necessary connection with complicated researchers. each one quantity of Advances in Inorganic Chemistry includes an index, and every bankruptcy is absolutely referenced. . accomplished stories written by way of top specialists within the box . An integral connection with complicated researchers . contains 7 contributions overlaying vital advances in inorganic chemistry

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HCrOÀ 4 þ Craq þ 3H ð30Þ SCHEME 7. The mechanism in Scheme 7 takes into account all the experimental observations and known chemistry of peroxyl radicals and various chromium species in the oxidation states 3 to 6. The dissociation of O2 from the tetroxide in reaction 27a may initially produce a short-lived m-peroxide (150), which undergoes an intramolecular electron transfer and hydrolysis to yield CrVaqO3 þ and acetic acid. The homolytic cleavage of the m-peroxide to CrIVaqO2 þ and CH3C(O)O is ruled out by the absence of CO2 and  CH3, the decarboxylation products of CH3C(O)O.

Biol. 2000, 11, 554^564. 31. ; Karlin, K. D. Models of copper enzymes and heme-copper oxidases, ‘‘Biomimetic Oxidations Catalyzed by Transition Metal Complexes’’; Ed. ; Imperial College Press: London, 2000, pp. 309^362. 32. Fokin, A. ; Schreiner, P. R. Chem. Rev. 2002, 102, 1551^1593. 33. ; Gorun, S. M. Methane monooxygenase models, ‘‘Biomimetic Oxidations Catalyzed by Transition Metal Complexes’’; Ed. ; Imperial College Press: London, 2000, pp. 269^307. 34. -J. Iron-containing models of catechol dioxygenases, ‘‘Biomimetic Oxidations Catalyzed by Transition Metal Complexes’’; Ed.

15. ; Gherman, B. ; Lippard, S. ; Friesner, R. A. Curr. Op. Chem. Biol. 2002, 6, 236^242. 16. Kopp, D. ; Lippard, S. J. Curr. Op. Chem. Biol. 2002, 6, 568^576. 17. Lipscomb, J. ; Que, L. Jr. J. Biol. Inorg. Chem. 1998, 3, 331^336. 18. Shteinman, A. A. J. Biol. Inorg. Chem. 1998, 3, 325^330. 19. Que, L. ; Tolman, W. B. Angew. Chem. Int. Ed. 2002, 41, 1114^1137. 20. Blackman, A. ; Tolman, W. B. Struct. Bonding (Berlin) 2000, 97 (Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations), 179^211.

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