Download Bioinspiration and Biomimicry in Chemistry: by Gerhard Swiegers, Jean-Marie Lehn, Janine Benyus PDF

By Gerhard Swiegers, Jean-Marie Lehn, Janine Benyus

Will we emulate nature's know-how in chemistry?Through billions of years of evolution, Nature has generated a few impressive platforms and elements that experience made existence on the earth what it's this present day. more and more, scientists are looking for to imitate Nature's structures and tactics within the lab for you to harness the facility of Nature for the advantage of society.Bioinspiration and Biomimicry in Chemistry explores the chemistry of Nature and the way we will be able to mirror what Nature does in abiological settings. in particular, the booklet specializes in absolutely synthetic, man-made structures that hire or are encouraged through ideas of Nature, yet which don't use fabrics of organic origin.Beginning with a normal assessment of the idea that of bioinspiration and biomimicry in chemistry, the ebook tackles such subject matters as:Bioinspired molecular machinesBioinspired catalysisBiomimetic amphiphiles and vesiclesBiomimetic ideas in macromolecular scienceBiomimetic cavities and bioinspired receptorsBiomimicry in natural synthesisWritten by means of a group of top foreign specialists, the contributed chapters jointly lay the basis for a brand new iteration of environmentally pleasant and sustainable fabrics, prescribed drugs, and applied sciences. Readers will detect the most recent advances in our skill to duplicate usual platforms and fabrics in addition to the numerous impediments that stay, proving how a lot we nonetheless have to find out about how Nature works.Bioinspiration and Biomimicry in Chemistry is suggested for college students and researchers in all nation-states of chemistry. Addressing how scientists are operating to opposite engineer Nature in all parts of chemical learn, the publication is designed to stimulate new dialogue and study during this fascinating and promising field.

Short description
This publication stories and summarizes the various and sundry sorts of bioinspiration and biomimicry which are present in chemistry, from the crude to the hugely subtle, from the near-biological to the utterly business and abiological. It severely evaluates our precise knowing of organic approaches and platforms by way of contemplating our skill to duplicate them in non-biological settings. examine chemists will locate severe and holistic assessment of chemical procedures in nature.

From the contents
Foreword xvii
Jean-Marie Lehn

Foreword xix
Janine Benyus

Preface xxiii

Contributors xxv

1. creation: the concept that of Biomimicry and Bioinspiration in Chemistry 1
Timothy W. Hanks and Gerhard F. Swiegers
1.1 what's Biomimicry and Bioinspiration? 1
1.2 Why search idea from, or reflect Biology? 3
1.3 different Monikers: Bioutilization, Bioextraction, Bioderivation, and Bionics 5
1.4 Biomimicry and Sustainability 5
1.5 Biomimicry and Nanostructure 7
1.6 Bioinspiration and Structural Hierarchies 9
1.7 Bioinspiration and Self-Assembly 11
1.8 Bioinspiration and serve as 12
1.9 destiny views: Drawing proposal from the complicated procedure that's Nature 13

2. Bioinspired Self-Assembly I: Self-Assembled buildings 17
Leonard F. Lindoy, Christopher Richardson, and Jack okay. Clegg
2.1 advent 17
2.2 Molecular Clefts, tablets, and Cages 19
2.3 Enzyme Mimics and versions: the instance of Carbonic Anhydrase 28
2.4 Self-Assembled Liposome-Like structures 30
2.5 Ion Channel Mimics 32
2.6 Base-Pairing buildings 34
2.7 DNA-RNA constructions 36
2.8 Bioinspired Frameworks 38
2.9 end 41

3. Bioinspired Self-Assembly II: ideas of Cooperativity in Bioinspired Self-Assembling platforms 47
Gianfranco Ercolani and Luca Schiaffino
3.1 advent 47
3.2 Statistical components in Self-Assembly 48
3.3 Allosteric Cooperativity 50
3.4 potent Molarity 52
3.5 Chelate Cooperativity 55
3.6 Interannular Cooperativity 60
3.7 balance of an meeting 62
3.8 end 67

4. Bioinspired Molecular Machines 71
Christopher R. Benson, Andrew I. proportion, and Amar H. Flood
4.1 advent 71
4.2 Mechanical results in organic Machines 78
4.3 Theoretical issues: Flashing Ratchets 83
4.4 Sliding Machines 86
4.5 Rotary vehicles 102
4.6 relocating greater Scale gadgets 104
4.7 strolling Machines 106
4.8 inventive Machines 109
4.9 utilizing artificial Bioinspired Machines in Biology 111
4.10 viewpoint 111
4.11 end 116

5. Bioinspired fabrics Chemistry I: Organic-Inorganic Nanocomposites 121
Pilar Aranda, Francisco M. Fernandes, Bernd Wicklein, Eduardo Ruiz-Hitzky, Jonathan P. Hill, and Katsuhiko Ariga
5.1 creation 121
5.2 Silicate-Based Bionanocomposites as Bioinspired platforms 122
5.3 Bionanocomposite Foams 124
5.4 Biomimetic Membranes 126
5.5 Hierarchically Layered Composites 129
5.6 end 133

6. Bioinspired fabrics Chemistry II: Biomineralization as suggestion for fabrics Chemistry 139
Fabio Nudelman and Nico A. J. M. Sommerdijk
6.1 notion from Nature 139
6.2 studying from Nature 144
6.3 utilising classes from Nature: Synthesis of Biomimetic and Bioinspired fabrics 146
6.4 end 160

7. Bioinspired Catalysis 165
Gerhard F. Swiegers, Jun Chen, and Pawel Wagner
7.1 advent 165
7.2 A normal Description of the Operation of Catalysts 168
7.3 a short background of Our realizing of the Operation of Enzymes 169
7.4 consultant reviews of Bioinspired/Biomimetic Catalysts 177
7.5 the connection among Enzymatic Catalysis and Nonbiological Homogeneous and Heterogeneous Catalysis 192
7.6 chosen High-Performance NonBiological Catalysts that take advantage of Nature's Catalytic ideas 193
7.7 end: The customers for Harnessing Nature's Catalytic ideas 203

8. Biomimetic Amphiphiles and Vesicles 209
Sabine Himmelein and Bart Jan Ravoo
8.1 creation 209
8.2 artificial Amphiphiles as development Blocks for Biomimetic Vesicles 210
8.3 Vesicle Fusion brought about by means of Molecular attractiveness 216
8.4 Stimuli-Responsive form regulate of Vesicles 224
8.5 Transmembrane Signaling and Chemical Nanoreactors 231
8.6 towards better Complexity: Vesicles with Subcompartments 239
8.7 end 245

9. Bioinspired Surfaces I: Gecko-Foot Mimetic Adhesion 251
Liangti Qu, Yan Li, and Liming Dai
9.1 The Hierarchical constitution of Gecko toes 251
9.2 foundation of Adhesion in Gecko Setae 252
9.3 Structural necessities for man made Dry Adhesives 253
9.4 Fabrication of man-made Dry Adhesives 254
9.4.1 Polymer-Based Dry Adhesives 254
9.4.2 Carbon-Nanotube-Based Dry Adhesives 278
9.5 Outlook 284

10. Bioinspired Surfaces II: Bioinspired Photonic fabrics 293
Cun Zhu and Zhong-Ze Gu
10.1 Structural colour in Nature: From Phenomena to starting place 293
10.2 Bioinspired Photonic fabrics 296
10.3 end and Outlook 317

11. Biomimetic ideas in Macromolecular technology 323
Wolfgang H. Binder, Marlen Schunack, Florian Herbst, and Bhanuprathap Pulamagatta
11.1 advent 323
11.2 Polymer Synthesis as opposed to Biopolymer Synthesis 325
11.3 Biomimetic Structural positive aspects in artificial Polymers 330
11.4 flow in Polymers 343
11.5 Antibody-Like Binding and Enzyme-Like Catalysis in Polymeric Networks 352
11.6 Self-Healing Polymers 355

12. Biomimetic Cavities and Bioinspired Receptors 367
Stephane Le Gac, Ivan Jabin, and Olivia Reinaud
12.1 advent 367
12.2 Mimics of the Michaelis-Menten Complexes of Zinc(II) Enzymes with Polyimidazolyl Calixarene-Based Ligands 368
12.3 Combining a Hydrophobic hollow space and A Tren-Based Unit: layout of Tunable, flexible, yet hugely Selective Receptors 377
12.4 Self-Assembled Cavities 383
12.5 end 391

13. Bioinspired Dendritic Light-Harvesting platforms 397
Andrea M. Della Pelle and Sankaran Thayumanavan
13.1 advent 397
13.2 Dendrimer Architectures 399
13.3 digital strategies in Light-Harvesting Dendrimers 403
13.4 Light-Harvesting Dendrimers in fresh strength applied sciences 407
13.5 end 413

14. Biomimicry in natural Synthesis 419
Reinhard W. Hoffmann
14.1 advent 419
14.2 Biomimetic Synthesis of average items 420
14.3 Biomimetic Reactions in natural Synthesis 437
14.4 Biomimetic concerns as an reduction in Structural project 447
14.5 Reflections on Biomimicry in natural Synthesis 448

15. end and destiny views: Drawing idea from the complicated method that's Nature 455
Clyde W. Cady, David M. Robinson, Paul F. Smith, and Gerhard F. Swiegers
15.1 advent: Nature as a posh procedure 455
15.2 universal positive factors of complicated platforms and the goals of structures Chemistry 457
15.3 Examples of study in platforms Chemistry 460
15.4 end: structures Chemistry could have Implications in different Fields 468

References 470

Index 473

Show description

Read Online or Download Bioinspiration and Biomimicry in Chemistry: Reverse-Engineering Nature PDF

Similar biomedical engineering books

Theoretical Molecular Biophysics

"Theoretical Molecular Biophysics" is a sophisticated learn booklet for college students, almost immediately sooner than or after finishing undergraduate reports, in physics, chemistry or biology. It presents the instruments for an figuring out of simple approaches in biology, corresponding to photosynthesis on a molecular point. A uncomplicated wisdom in mechanics, electrostatics, quantum idea and statistical physics is fascinating.

Mathematical Theory of Electrophoresis

The improvement of latest molecular biology with its growing to be tendency towards in-depth research of the mechanisms of organic approaches, constitution, functionality, and identity of biopolymers calls for software of actual physicochemical tools. Electrophoresis occupies a key place between such equipment.

Interpreting Biomedical Science: Experiment, Evidence, and Belief

Analyzing Biomedical technological know-how: scan, facts, and trust discusses what can get it wrong in organic technology, delivering an impartial view and cohesive realizing of medical tools, statistics, facts interpretation, and medical ethics which are illustrated with useful examples and real-life functions.

Additional resources for Bioinspiration and Biomimicry in Chemistry: Reverse-Engineering Nature

Sample text

Annu. Rev. Mater. Res. 2010. 40, 179. 29. Vincent, J. F. V. Proc. Inst. Mech. Eng. H: J. Eng. Med . 2009, 223, 919. 30. Deuss, P. ; Kamer, P. C. J. Chem. Eur. J . 2011, 17, 4680. 31. ; Deprez, B. Chem. Biol. Drug Des. 2008, 72, 3. 32. Johnson, E. A. ; Bonser, R. H. ; Jeronimidis, G. Philos. Trans. R. Soc. A 2009, 367, 1559. 33. ; Ungaro, R. New J. Chem. 2010, 34, 2715. CHAPTER 2 Bioinspired Self-Assembly I: Self-Assembled Structures LEONARD F. LINDOY School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia CHRISTOPHER RICHARDSON School of Chemistry, University of Wollongong, Wollongong, NSW 2522, Australia JACK K.

Vincent, J. F. ; Bogatyreva, O. -P. J. R. Soc. Interface 2006, 3, 471. 3. Busch, D. H. Abs. Papers Am. Chem. Soc. 1976, Suppl. I , 1. 4. Benyus, J. M. Biomimicry: Innovation Inspired by Nature, William Morrow, New York, 1997. 5. org/. 6. ; Cocero, M. J. Chem. Eng. J . 2007, 133, 7. 7. Ginatta, C. ARCHITECTURE Without Architecture: Biomimicry Design, VDM Verlag Dr. M¨uller GmbH & Co. KG, Saarbrucken, Germany, 2010. 8. Gruber, P. Biomimetics in Architecture: Architecture of Life and Buildings, Springer, New York, 2011.

Yet the actual realization of the examples offered is difficult, as it requires not only understanding the material’s composition and properties at the different length scales, but also the ways in which they work together to provide the properties of interest. S. ) has been spent by the public and private sectors, with many nations instituting formal nanotechnology programs. The global focus on nanotechnology has accelerated the ongoing development of imaging and analytical tools that bridge the gap between the traditional chemistry size regime and that of biology.

Download PDF sample

Rated 4.37 of 5 – based on 25 votes