By Malcolm Sainsbury
Hardbound. a number of extremely important components of fragrant chemistry are spanned during this quantity. It contains chapters dedicated to benzoquinones, nitro compounds, metallo derivatives and fragrant hydrocarbons with substituents which include a couple of nitrogen atom, e.g., azobenzenes, azides, and so on.
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Extra info for Chemistry of Carbon Compounds: 2nd Supplement to 2r.e v.3B, C, D
Miyaura and A. Suzuki, Chem. , 1993, 845). It has also been obtained by an improved (potassium iodide - crown-6) Finkelstein elimination from (~,o~'-dibromo-o-xylene, and trapped with buckminsterfullerene (C6o) (P. , Angew. Chem. Int. Ed. , 1993, 32, 78); various substituted 1,2-benzoquinone dimethides, prepared by the thermolysis of benzocyclobutenes, also form adducts with C60 (A. , Angew. Chem. Int. Ed. , 1994, 3,3,559; M. , J. Chem. , Chem. , 1994, 1929). P. L. Charlton, J. Org. , 1993, 5_88,4132), and by treatment of the corresponding 13-substituted o(tributylstannylmethyl)styrenes with arylsulfenyl chlorides (H.
Oda, J. Org. , 1988, 53, 216). G. P. Collis, J. Chem. , Chem. , 1991, 1343). ~ Benzoquinols (Hyd roxycyclohexadienones) The most widely used methods of preparation involve the oxidation of ortho or para substituted phenols, particularly alkylphenols, but also 4-arylphenols, with phenyliodine bisacetate or trifluoroacetate (A. Varvoglis, "The Organic Chemistry of Polycoordinated Iodine", VCH, Weinheim, 1992; A. , J. Chem. , Perkin Trans. 1, 1992, 2246; 1993, 1891; P. , J. Org. , 1993, 5_68,1649, 7195; M.
Moore and R. Czerniak, Med. Res. G. Peter, Angew. Chem. Int. Ed. E. C. -Biol. Interactions, 1992, 86, 129). Further, 1,4-benzoquinone monomethides are involved in the sclerotisation (tanning) of insect cuticle (M. , Arch. Insect Biochem. , 1991,279, 145; J. Biol. , 1992, 267, 10355), and in the biosynthesis of melanins (M. Sugumaran, H. Dali and V. Semensi, Bioorg. , 1990, 18, 144) and eumelanins (M. Sugumaran and V. Semensi, J. Biol. , 1991, 266, 6073). R. D. Turnbull, J. Org. M. G. Apushkinskii, Russ.