Download Chemistry of Superconductor Materials: Preparation, by C. W. Gardiner, P. Zoller PDF

By C. W. Gardiner, P. Zoller

This thorough evaluation of the chemistry of excessive Tc superconductors presents wide insurance of the structural and artificial solid-state chemistry of oxide superconductors in addition to significant reference fabric on characterization equipment. Written via 27 experts within the box, the booklet fulfills a necessity for a condensed, single-source reference. it is going to be critical for researchers and for these unusual with structural and artificial solid-state chemistry of superconductors.

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Extra resources for Chemistry of Superconductor Materials: Preparation, Chemistry, Characterization and Theory (Materials Science and Process Technology Series)

Example text

M TomperatureIK Figure 6: The original plot of relative resistance (T / K) for “SnO”, as published in Reference 6. W~SUStemperature Historical Introduction and Crystal Chemistry of Oxide Superconductors to generate interesting superconductors in much materials adopting a cubic crystal structure. 6 Ventures Systems into Ceramic Oxides- 17 the same way as Simple Binary and Ternary If carbides, nitrides, and borides could generate such intriguing T, values, what promise did the ceramic, metallic-conducting oxides hold?

These oxides can be classified into separate groups: binary oxides = 12; ternary oxides = 22; and multinary or complex oxides = 8. 3 K for nearly stoichiometric TiO. In 1978, Roberts presented (11) an addendum to his 1975 data set with the addition (or revision) of 8 new (mostly superconducting) oxides. Metal-rich binary systems (also referred to as metallic sub-oxides), however, exhibited slightly higher transition temperatures than the stoichiometric oxide compounds, but for these interstitials the T, was never any higher than that of the superconducting metal.

33WO3 Rho. 3oW03 hexag. 8 57 CsO. 32WO3 hexag. 12 59, CsO. 2oW03 hexag. 7 69 Cso. 3oW03 hexag. 10W03 hexag. O8W03 hexag. 12 70 60 Ammonium compound (NH4J0. 13W03 bl. 1 F3 hexag. compounds tetrag. I hexag. Mi SC. compounds Cue. 32W03 hexag. 11W03 hexag. 11W03 hexag. 8 63 TIO. 3oW03 hexag. 58 65 TIo. 3oW03 hexag. 14 63 sno. 19W03 tetrag. 21W03 hexag . 3 57 snO. 24w03 hexag . 8 60 oxyf luorides. 4 66 (filament& plate) Cs,WO374 C~xLiyWO3,xFx+y "MolybdenumEkonze'l Systems. 5Mo03 tetrag. 6 18 Bronze11Systems.

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