By Carla Armanino, Michele Forina, Philip H.E. Gardiner, E.J. van den Heuvel, Gerrit Kateman, Silvia Lanteri, H.C. Smit, Bernard G.M. Vandeginste
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Additional info for Chemometrics and Species Identification (Topics in Current Chemistry)
Co, where R 0 is a vector of responses, obtained for the sample at NW sensors, K is the matrix of NW calibration factors of NA analytes, Co is the vector of the concentrations of NA analytes, in the sample. The calibration of the system and the determination of the concentrations of the analytes are carried out in two steps. 33 Bernard G. M. Vandeginste First the responses R0 are measured for the sample. Thereafter K is determined by fitting the changes in the concentrations of the anatytes in the sample, brought about by the standard additions, to the changes in the responses.
The eigenvalues of an excitation-emissiondatamatrix (EEM) of a 3-component mixture of polycyclicaromates, as a function of the factor aK, with which the EEM of ethyl benzene is removed. From M. McCue and E. R. Malinowski,J. Chromatogr. Sci. 21, 233 (1983). , Niles, Illinois solve binary mixtures 1 0 6 ) A scheme which gives the accuracy of the estimated spectra, given as a function of spectral overlap can be found in lo6~ Because emission spectra are strongly correlated with the excitation spectra the EEM datamatrix does not contain much qualitative information in addition to the regular absorbance spectrum.
Ibid. 54, 560 (1982) 119. Bos, M. :Anal. Chim. Acta 166, 261 (1984) 120. , Jensen, S. A. : "Partial least squares regression: A new two-stage NIR calibration method" in Proceedings of the 7-th World Cereal and Bread Congress, Prague, 1982, Elsevier, Amsterdam, in press 121. Mandel, J. : The American Statistician 36 (1), 15 (1982) 122. , Martens, H. : Anal. Chim. Acta 150, 61 (1983) 123. ) 1983 124. Kowalski, B. , Russwurm, jr. H. ) 1983 125. O'Haver, T. : Trends Anal. Chem. 4 (8), 191 (1985) 126.