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1 Fullerenes – Carbon Soccer Balls We used to believe that there are three allotropic forms of carbon: graphite, diamond, and amorphous carbon. However, an important new carbon allotrope, the fullerenes, was discovered as recently as the 1980s. The most famous fullerene is buckminsterfullerene, C60 , which is depicted in Fig. 1. The structure of this “soccer ball-shaped” molecule consists of a sphere of sixty carbon atoms arranged in pentagons and hexagons; each carbon pentagon is surrounded by five carbon hexagons.

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Chem. B, 101, 4810 (1997) 89. H. Tamagawa, M. Sakurai, Y. Inoue, K. Ariga, T. Kunitake, “ Theoretical Study of Intermolecular Interaction at the Lipid–Water Interface. 2. Analysis Based on the Poisson–Boltzmann Equation”, J. Phys. Chem. B, 101, 4817 (1997) 90. Y. Sasaki, K. Kurihara, T. Kunitake, “Specific Multi-Point Binding of ATP and AMP to a Guanidinium-Functionalized Monolayer”, J. Am. Chem. , 113, 9685 (1991) 91. M. Onda, K. Yoshihara, H. Koyano, K. Ariga, T. Kunitake, “Molecular Recognition of Nucleotides by the Guanidinium Unit at the Surface of Aqueous Micelles and Bilayers.

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