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This booklet had its nucleus in a few lectures given by means of one ofus (J. O'M. B. ) in a path on electrochemistry to scholars of power conversion on the Vniversity of Pennsylvania. It was once there that he met a couple of humans informed in chemistry, physics, biology, metallurgy, and fabrics technology, all ofwhom desired to recognize anything approximately electrochemistry.
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L. Hill, Statistical Thermodynamics, Addison-Wesley, Reading, MA, 1962. 13. B. E. Conway, in Comprehensive Treatise of Electrochemistry, Vol. 5, B. E. Conway, J. O’M. Bockris, and E. , Plenum Press, New York, 1982. 14. J. E. Desnoyers and C. Jolicoeur, in Comprehensive Treatise of Electrochemistry, Vol. 5, B. E. Conway, J. O’M. Bockris, and E. , Plenum Press, New York, 1982. 15. B. E. Conway, in Physical Chemistry: An Advanced Treatise, Vol. 9A, H. , Academic Press, New York, 1970. 16. H. L. Friedman, J.
15. B. E. Conway, in Physical Chemistry: An Advanced Treatise, Vol. 9A, H. , Academic Press, New York, 1970. 16. H. L. Friedman, J. Electrochem. Soc. 124, 421C (1977). 17. J. O’M. Bockris and S. U. M. Khan, Surface Electrochemistry, Plenum Press, New York, 1993. 1. Calculate the heat of hydration of NaCl and KCl from the following experimental data. 4 kcal/mol. 2. Derive Eq. 23) from Eq. 22). 3. Derive Eq. 32) from Eq. 023 ϫ 1023 molϪ1. Note that ni in Eq. 32) denotes the number of i-type ions per liter and c is the concentration in mol/L.
The diffuse double layer extends from the distance xH to the bulk of the solution. 9. The plane at the distance xH from the electrode is called the Helmholtz plane (HP) or the plane of closest approach. The dividing HP is taken to be the locus of centers of fixed hydrated ions (Fig. 9). According to Stern, ions cannot come closer to the electrode than the plane of closest approach (HP). This postulate eliminates the pointcharge approximation of the Gouy–Chapman theory. The separation of the interphase into two regions is equivalent to separation of the total double-layer capacitance as due to two contributions: CH, the Helmholtz capacity, and the CGC, the Gouy–Chapman capacity.