Download Macromolecules Containing Metal and Metal-Like Elements, by Alaa S. Abd-El-Aziz, Charles E. Carraher, Charles U. PDF

By Alaa S. Abd-El-Aziz, Charles E. Carraher, Charles U. Pittman, John E. Sheats, Martel Zeldin

Steel and metalloid-containing compounds convey quite a lot of organic and biocidal actions, a few of that have been hired in drugs and medication. Polymers containing steel or metalloid capabilities develop into a normal extension of this attempt; simply as natural compound medicinal drugs were chemically certain to polymers or bodily imbibed into polymer matrices in an effort to supply a number of worthy merits, an analogous possibilities exist for utilizing steel and metalloid species. This quantity will conceal vital biomedical purposes of organometallic compounds, together with metal-labeled DNA on surfaces, synthetic metallo-DNA, organotin molecules as anti-cancer medicinal drugs, and masses extra.

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6) at (a) a bare gold electrode and (b) a M-DNA-modified gold electrode. Simulated data are indicated as (O) (scan rateϭ100 mV/s. 21 (vs. 19 V (vs. 4. The diffusion coefficients of Dox and Dred used for (a) were 8ϫ10Ϫ6 cm2/s for the [Fe(CN)6]3Ϫ/4Ϫ couple. Figure 14 Nyquist plots of a 20-mer of ds-DNA ( ) and M-DNA ( ). The spectra were fit to the equivalent circuit shown on the top left; individual elements of the equivalent circuit are summarized below: charge transfer resistance RCT, Warburg impedance W, and interfacial resistance Rx.

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