Download Química inorgánica by James E. Huheey, Elle A. Keiter, Richard L. Keiter PDF

By James E. Huheey, Elle A. Keiter, Richard L. Keiter

Los autores exponen en esta obra el conjunto primary de temas que conforman esa disciplina, así como algunos otros que los estudiantes y los maestros pueden encontrar interesantes.

Completamente actualizado, el libro incluye una introducción a los grupos puntales, un nuevo capítulo sobre simetría, otro sobre enlace y otros más que incluyen espectroscopia y cristalografía, todos ellos profusamente ilustrados y ejemplificados con objeto de ser más entendibles.

Los lectores de esta obra pueden provenir de ramas diversas, con experiencia en fisicoquímica y química orgánica. Sin embargo, para muchos este libro será el primer contacto con los angeles química inorgánica, por lo que los primeros capítulos presentan los fundamentos de l. a. estructura atómica y molecular desde los angeles perspectiva de los angeles química inorgánica.

Al terminar el estudio del libro, se espera que el estudiante comprenda cabalmente l. a. enorme diversidad de l. a. química inorgánica, los angeles cual estudia 109 elementos, cada uno con sus propias características.

Estudio de estructuras, reactividad, catalizadores, estabilidad termodinámica, simetría, técnicas experimentales, fases gaseosas, soluciones, química del estado sólido, entre otros.

Desde los primeros tiempos, el hombre se interesó por aprovechar los minerales en beneficio propio. Sin embargo, sus conocimientos eran pragmáticos. Con el tiempo, el conocimiento sobre los minerales se aplicó a los angeles extracción de metales preciosos y, de ese modo, l. a. química inorgánica fue ganando terreno hasta convertirse en los angeles base teórica para los angeles explotación racional no sólo de los minerales, sino de las moléculas y átomos que los componen.

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1975,45, 686. 3~ The formation of (41 ;R = H) from the action of base on the salt (42) supports a mechanism via the intermediate ylides (43). The crystalline cyclic acyloxy- or amido-phosphoranes (45) were obtained in high yield from the cyclic phosphonite (44)and acrylic acid or acrylamide respectively under mild c ~ n d i t i o n s . 37cis-Cyclohexane- h ~CL, + CEICI, Wil 35 36 37 A. Turcant and M. Le Come, Tetrahedron Letters, 1976, 1277. T. Saegusa, S. Kubayashi, and Y . S. Chem. ,1976,443.

R. 46On the basis of its 31Pchemical shift in DMF solution, (108)was formulatedss as the free six-co-ordinate acid (110), but it seems probable that DMF is 65 F. Ramirez, J. F. Marecek, I. Ugi, P. Lemmen, and D. Marquarding, Phosphorus, 1975, 5, 73. M. F. Pommeret-Chasle, A. Leduc, and M. Hassairi, Tetrahedron, 1975,31,2775. 66 J. Gloede and H. Gross, Tetrahedron Letters, 1976, 917. 64 Quinquecovalent Phosphorus Compoiinds 47 (108) sufficiently basic to give a salt corresponding to (109) in solution.

Borisova, and I. M. Shermergorn,J . Gen. Chem. ), 1975,45,929 e2 K. -D. Roth, K. Einhellig, and L. Hatzelmann, Chem. , 1975, 108, 2737. 63 J. Albanbauer, K. Burger, E. Burgis, D. Marquarding, L. Schabl, and I. Ugi, Annalen, 1976,36. ~~ That from (101;R = OMe) probably had the relationship of methoxy to ring junction shown in (102);it slowly isomerized in solution at 40 "C to a 60:40 mixture with the isomer (103). The corresponding isomerizations were rapid in the case of the chloro- and dimethylamino-analogues.

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