By J. J. Zuckerman, Arlan D. Norman
For the 1st time the self-discipline of contemporary inorganic chemistry has been systematized in accordance with a plan built by means of a council of editorial advisors and specialists, between them 3 Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). instead of generating a set of unrelated assessment articles, the sequence creates a framework which displays the artistic power of this medical self-discipline. therefore, it stimulates destiny improvement via picking parts that are fruitful for extra learn. The paintings is listed in a distinct manner by way of a based process which maximizes its usefulness to the reader. It augments the association of the paintings through offering extra routes of entry for particular compounds, reactions and different issues.
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Extra info for Reactions Catalyzed by Inorganic Compounds
Am. Chem. ,107,4333 (1985). 6. Insertion Reactions The term insertion reactions (see Section 11) designates a rather broad collection of processes in which the overall reaction corresponds to insertion of an unsaturated molecule (X) into a metal-ligand (M-Y) bond’. Variants of processes encompassed by this designation are depicted schematically by X L I M-Y M-Y M-X +X +Y -- M-X-Y (- L I M-X-Y) (a) M-X-Y (b) M-X-Y (c) Familiar combinations include Y = H, X = olefin, acetylene, or diene; Y = alkyl, X = CO; Y = OH or OR, X = CO or olefin.
Am. Chem. , 99, 2134 (1977). 13. I. E. Bercaw, R. H. Marvich, L. G. Bell, H. H. Brintzinger,J. Am. Chem. , 94,1219 (1972). 14. J. L. Thomas,J. Am. Chem. , 95, 1838 (1973). 15. F. N. Tebbe, G. W. Parshall, J. Am. Chem. ,93, 3793 (1971). 16. L. Abis, A. Sen, J. Halpem, J. Am. Chem. ,100,2915 (1978). 3. Free Radical Chain Mechanism of Oxidative Addition. 21 is disfavored for steric reasons, the same overall reaction may be achieved by a free radical chain mechanism: Initiation: Propagation: + Ir(1) R-Ir(I1) + RX R' Overall Reaction: Ir(1) -- + RX R-Ir(1I) R-Ir(II1)X + R' R-Ir(II1)X (4 Such a mechanism has been identified for the oxidative addition of cyclo-C,H, ,Br to [IrCl(CO)(PPh,),] I.
John Wiley, New York, 1967, p. 23. 3. J. Halpem, Comments Inorg. , 1 , 3 (1981), and references therein. 4. J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, Principles and Applications of Organotransition Metal Chemistry, Ch. 7, University Science Books, Mill Valley, CA, 1987. 5. J. E. Bercaw, L. Y. Goh, J. Halpem, J. Am. Chem. ,94, 6534 (1978). 6. P. M. Henry, Palladium Catalyzed Oxidations of Hydrocarbons, D. Reidel, Dordrecht, Holand, 1980. 7. J. E. Backvall, B. Akermark, S. 0. Ljunggren, J .