By V. M. Rozenbaum, S. H. Lin
Read or Download Spectroscopy and Dynamics of Orientationally Structured Adsorbates (World Scientific Lecture and Course Notes in Chemistry, Volume 7) PDF
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Extra resources for Spectroscopy and Dynamics of Orientationally Structured Adsorbates (World Scientific Lecture and Course Notes in Chemistry, Volume 7)
Y,o). 5. 10) at which the order parameter rjy vanishes (see Fig. 21). As temperature increases further, the vector (jemn) becomes oriented along the horizontal axis of the square lattice, whereas the average positions of molecular axes at the neighboring lattice sites form T-like structures just as in the ground state of a quadrupole system in the absence of selected orientations. 0421/. 5 \\ 1\ • 4 - kBT/U Fig. 21. mn)(3) and the specific heat C/NkB (4, the right-hand ordinate axis) for the model with four discrete orientations.
11)). The strong intrachain dipole interaction cannot ensure long-range order in an isolated chain and low phase transition temperatures are thus caused by the small value of interchain interactions. Good estimates of transition temperatures Tc which consider the small value of interchain interactions are obtainable using a generalized approximation of an interchain self-consistent field62'63 which involves an exact solution of a onedimensional Ising model with short-range interaction HQ = -2V .
The two-sublattice structure given by