By F P IJsseling; European Federation of Corrosion
Crevice corrosion is a fancy and technically attention-grabbing corrosion mechanism yet its advertisement value shouldn't be missed. This survey, the main whole assessment on crevice corrosion to be had this present day, covers many alloys that may undergo crevice assault yet focuses in most cases on stainless steels. The survey covers mechanisms, try out tools and effects, sensible adventure, protecting measures and tracking.
desk of Contents
2. idea and Modelling of Mechanisms
three. try equipment
four. Mechanisms, stipulations, functions and Experimental result of particular Alloy forms
five. defense opposed to Crevice Corrosion
6. Crevice Corrosion tracking
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Extra resources for Survey of Literature on Crevice Corrosion (1979-1998) - Prepared by Ijsseling, F.P. and the Working Party on Marine Corrosion
After Gnrtlniid nnd Vnleii 191,1931. 2. by direct measurement of the current between a small uncreviced anode in contact with a simulated crevice solution and a large uncreviced cathode; 3. from separately determined polarisation curves; 4. from the slope of anodic peak current vs pH; 5. from polarisation resistance measurements; and 6. by mathematical modelling. 1. zeasiirenzeiit of the ciirrerit betzoeeiz creviced aizode and m z icricreviced cn fhode This method can be performed in a single compartment cell (Fig.
Matheinatical nod el ling This requires various input parameters, such as alloy composition, crevice geometry, chloride level of bulk solution, temperature, and so on . In addition the method also requires two inputs which have to be determined electrochemically: the critical crevice solution (CCS) and the passive current [ 184,193,2051. Some examples of determining initiation characteristics are given next. Lizlovs was among the first to perform potentiostatic tests with creviced samples .
24 Deterininntioil ofrepassivntion poteritinl: (a) byfirst increasing the potential (linearly or iiz steps) until iiiitintioiz is observed, uhereupoiz the potential is lowered until Erepassis reached; ( h ) by starti ng nt high controlled poterztinl to prozvke initiation, nnd then procedure A isfollozoed. The same methodology is used as in determining Erepnss(see above and Fig 19c). The second method is by applying a high level of potential and temperature to provoke initiation, and when this has occurred and a certain amount of charge has passed during propagation one or both parameters are lowered until repassivation is observed (Figs 27 and 28).