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Additional resources for The Application of Wave Mechanical Methods to the Study of Molecular Properties (ADVANCES IN CHEMICAL PHYSICS)(VOLUME 8)

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And Ganguly, S. , Proc. Roy. Soc. (Lmdon) A259, 419 (1960). 4. Craig, D. , Proc. Roy. Soc. 271, 207 (1963). 5. Santry, D. , Thesis, University of London, 1962. 6. Craig, D. , and Philpott, M. , in press. 7. Koster, G. , and Slater, J. , Phys. Rev. 96, 1208 (1954); and earlier papers. Advance in Chemical Physics, Volume VIII Edited by R. Daudel Copyright © 1965 by John Wiley & Sons. Inc. APPLICATIONS OF LIGAND-FIELD THEORY TO COMPLEXES CHR. KLIXBULL JBRGENSEN, Cyanamid Euro$ean Research Institute, Cologny (Geneva),Switzerland Transition-group complexes combine some of the characteristics of “small” molecules, where a priori calculations are very difficult, with those of “large” molecules, where they are impossible.

130, 512 (1963). ,Helv. Phys. Acta 36, 530 (1963). ,Bull. A m . Phys. 8, 24 (1963). , and Lipscomb, W. , J . Chem. Phys. 39, 1007 (1963). , and Rosengarten, D. , J. Mol. Spectr. 12, 319 (1964). McClure, D. ,J . Chem. Phys. 38, 2289 (1963). ,J . Chem. Phys. 39, 2850 (1963). McFarlane, R. ,J . Chem. Phys. 39,3118 (1963). , and Chhonkar, N. , 'Indian J . Phys. 37, 375 (1963). , Phys. Rev. 132, 504 (1963). , J . MoZ. Spectr. 12, 98 (1964). Naiman, C. , and Linz, Arthur, Proceedings of the Symposium on Optical Masers, Polytechnic Press, Brooklyn, 1963,p.

I n these formulae, R indicates an atom bound by an “innocent” a-bond to the chromophore. In carbon compounds especially, it is quite evident that chromophores with internal fractional bondorders can be effectively separated by o-bonded chains, a most striking example being compoundsS1of the type Cl,,H,(CH,),C,4Hg where light quanta manifestly absorbed in the naphthalene part produce fluorescence in the anthracene group for n = 1 , 2, 3, whereas this process is much less probable for separated molecules in solution.

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